MAPETI A DATA YOTETEZEKA

Malinga ndi UN GHS revision 8

Mtundu: 1.0

Tsiku Lopangidwa: Julayi 15, 2019

Tsiku Lokonzanso: Julayi 15, 2019

GAWO 1: Chizindikiritso

1.1GHS Chizindikiritso chazinthu

1.2 Njira zina zozindikiritsira

1.3 Kugwiritsa ntchito molangizidwa kwa mankhwalawa ndi zoletsa pakugwiritsa ntchito

1.4 Zambiri za ogulitsa

1.5 Nambala yafoni yadzidzidzi

GAWO 2: Kuzindikiritsa zoopsa

2.1 Gulu la chinthu kapena kusakaniza

Zakumwa zoyaka moto, Gulu 1

Pachimake kawopsedwe - Gulu 3, Oral

Pachimake kawopsedwe - Gulu 3, Dermal

Kukwiya pakhungu, Gawo 2

Kupweteka m'maso, Gawo 2

Pachimake kawopsedwe - Gawo 2, Kupuma mpweya

Chiwopsezo cha chiwalo chandandandandandala - kuwonekera kamodzi, Gulu 3

Zowopsa m'malo am'madzi, akanthawi kochepa (Acute) - Gulu Lowopsa 1

Zowopsa ku chilengedwe cha m'madzi, kwanthawi yayitali (Zosatha) - Gulu 1

2.2GHS zolemba zolemba, kuphatikiza mawu osamala

2.3 Zowopsa zina zomwe sizimayika m'magulu

palibe deta yomwe ilipo

GAWO 3: Kupanga/zambiri pa zosakaniza

3.1 Zinthu

GAWO 4: Njira zothandizira chithandizo choyamba

4.1 Kufotokozera zofunikira zothandizira chithandizo choyamba

Ngati atakoka mpweya

Mpweya wabwino, pumulani.Theka-woongoka malo.Pitani kuchipatala.

Kutsatira kukhudza khungu

Chotsani zovala zowonongeka.Tsukani khungu ndi madzi ambiri kapena shawa.Pitani kuchipatala .

Kutsatira kuyang'ana maso

Muzimutsuka ndi madzi ambiri kwa mphindi zingapo (chotsani magalasi ngati nkotheka).Pitani kuchipatala msanga.

Kutsatira kumeza

Muzimutsuka pakamwa.OSATI kulimbikitsa kusanza.Perekani kapu imodzi kapena ziwiri madzi amwe.Pitani kuchipatala .

4.2 Zizindikiro / zotulukapo zofunika kwambiri, zowopsa komanso zochedwa

Kadulidwe ka ERG Guide 131 [Zamadzimadzi Oyaka - Poizoni]: POXIC;akhoza kupha ngati atakowetsedwa, atalowetsedwa kapena atamwa pakhungu.Kukoka mpweya kapena kukhudzana ndi zina mwazinthuzi kumakwiyitsa kapena kutentha khungu ndi maso.Moto udzatulutsa mpweya wokwiyitsa, wowononga komanso/kapena wapoizoni.Nthunzi zingayambitse chizungulire kapena kufufuma.Kuthamanga kwa moto kapena madzi osungunuka kungayambitse kuipitsa.(ERG, 2016)

4.3 Chisonyezero cha chithandizo chamankhwala mwamsanga ndi chithandizo chapadera chofunika, ngati kuli kofunikira

Thandizo loyambirira: Onetsetsani kuti kuwononga kokwanira kwachitika.Ngati wodwala sakupuma, yambani kupuma mochita kupanga, makamaka pogwiritsa ntchito chotsitsimutsa cha valve, chipangizo cha bag-valve-mask, kapena chigoba cha m'thumba, monga mwaphunzitsidwa.Chitani CPR ngati pakufunika.Yambani maso oipitsidwa ndi madzi oyenda pang'onopang'ono.Osayambitsa kusanza.Ngati kusanza kukuchitika, tsamirani wodwala kutsogolo kapena ikani kumanzere (malo opita kumutu, ngati kuli kotheka) kuti mukhale ndi njira yotseguka yolowera ndikupewa kulakalaka.Khalani chete oleza mtima ndikukhalabe ndi kutentha kwa thupi.Pezani chithandizo chamankhwala.Ketoni ndi mankhwala ogwirizana

GAWO 5: Njira zozimitsa moto

5.1 Makanema ozimitsa oyenera

Ngati zinthu zayaka kapena zakhudzidwa ndi moto: Musazimitse moto pokhapokha ngati madziwo atsekedwa.Zimitsani moto pogwiritsa ntchito chothandizira chomwe chili choyenera mtundu wamoto wozungulira.(Zinthu zokha siziwotcha kapena kupsa movutikira.) Muziziziritsa zotengera zonse zomwe zakhudzidwa ndi madzi osefukira.Ikani madzi kuchokera patali kwambiri.Gwiritsani ntchito thovu, mankhwala owuma, kapena carbon dioxide.Sungani madzi otuluka mu ngalande ndi magwero a madzi.Chloroacetone, yokhazikika

5.2 Zowopsa zenizeni zomwe zimadza chifukwa cha mankhwala

Kadulidwe ka ERG Guide 131 [Zamadzimadzi Zoyaka - Zapoizoni]: ZOMWE ZOYAKIRA KWAMBIRI: Zidzayatsidwa mosavuta ndi kutentha, zoyaka kapena malawi.Nthunzi zimatha kupanga zosakaniza zophulika ndi mpweya.Mpweya ukhoza kupita kugwero loyatsira ndikubwereranso.Nthunzi zambiri zimakhala zolemera kuposa mpweya.Adzafalikira pansi ndikusonkhanitsa m'malo otsika kapena otsekeka (zonyansa, zipinda zapansi, akasinja).Kuphulika kwa nthunzi ndi chiwopsezo chakupha m'nyumba, panja kapena m'zimbudzi.Zinthu zomwe zimapangidwa ndi (P) zimatha kupanga ma polymer kwambiri zikatenthedwa kapena zikawotchedwa.Kuthamangitsidwa kwa ngalande kungayambitse ngozi ya moto kapena kuphulika.Zotengera zimatha kuphulika zikatenthedwa.Zamadzimadzi zambiri ndi zopepuka kuposa madzi.(ERG, 2016)

5.3 Zochita zoteteza mwapadera kwa ozimitsa moto

Gwiritsani ntchito kupopera madzi, ufa, thovu losagwira mowa, mpweya woipa.Pakayaka moto: sungani ng'oma ndi zina zotero, kuziziziritsa popopera madzi ndi madzi.

GAWO 6: Njira zotulutsira mwangozi

6.1Kusamala kwanu, zida zodzitetezera ndi njira zadzidzidzi

Chotsani zoyatsira zonse.Chokani pamalo oopsa!Funsani katswiri!Chitetezo chaumwini: chopumira chosefera cha mpweya wa organic ndi nthunzi zomwe zimatengera kuchuluka kwa zinthu zomwe zimayendera ndi mpweya.Mpweya wabwino.Sonkhanitsani madzi akutha mu mbiya zophimbidwa.Yamwani madzi otsala mumchenga kapena zoyamwitsa zoziziritsa kukhosi.Kenako sungani ndikutaya motsatira malamulo akumaloko.

6.2 Chitetezo pazachilengedwe

Chotsani zoyatsira zonse.Chokani pamalo oopsa!Funsani katswiri!Chitetezo chaumwini: chopumira chosefera cha mpweya wa organic ndi nthunzi zomwe zimatengera kuchuluka kwa zinthu zomwe zimayendera ndi mpweya.Mpweya wabwino.Sonkhanitsani madzi akutha mu mbiya zophimbidwa.Yamwani madzi otsala mumchenga kapena zoyamwitsa zoziziritsa kukhosi.Kenako sungani ndikutaya motsatira malamulo akumaloko.

6.3Njira ndi zida zosungira ndi kuyeretsa

Kuganizira za chilengedwe - kutayikira kwa nthaka: Kukumba dzenje, dziwe, nyanja, malo osungiramo zinthu zamadzimadzi kapena zolimba./SRP: Ngati nthawi ilola, maenje, maiwe, madambo, maenje onyowa, kapena malo osungira ayenera kutsekedwa ndi liner yosalowa.Yankhani madzi ochuluka ndi phulusa la ntchentche, ufa wa simenti, kapena sorbents zamalonda.Chloroacetone, yokhazikika

GAWO 7: Kugwira ndi kusunga

7.1 Njira zodzitetezera pakusamalidwa bwino

POPANDA malawi otseguka, POPANDA zipsera, POPANDA kusuta.Pamwamba pa 35°C gwiritsani ntchito makina otsekedwa, mpweya wabwino komanso zida zamagetsi zosaphulika.Kusamalira pamalo abwino mpweya wokwanira.Valani zovala zoyenera zodzitetezera.Pewani kukhudzana ndi khungu ndi maso.Pewani kupanga fumbi ndi ma aerosols.Gwiritsani ntchito zida zopanda moto.Pewani moto woyambitsidwa ndi nthunzi ya electrostatic discharge.

7.2Makhalidwe osungira otetezeka, kuphatikiza zosagwirizana

Sungani pokhapokha ngati itakhazikika.Zosatentha ndi moto.Olekanitsidwa ndi okosijeni amphamvu ndi zakudya ndi zakudya.Khalani mumdima.Sungani pokhapokha ngati itakhazikika.Zosatentha ndi moto.Olekanitsidwa ndi zotulutsa zotulutsa zolimba, zakudya ndi zakudya.Khalani mumdima… Pamwamba pa 35 deg C gwiritsani ntchito makina otsekedwa, mpweya wabwino, ndi zida zamagetsi zomwe sizingaphulike.

GAWO 8: Zowongolera zowonetsera / chitetezo chamunthu

8.1 Control magawo

Makhalidwe ochepera a Occupational Exposure

TLV: 1 ppm monga STEL;(khungu)

Malire achilengedwe achilengedwe

palibe deta yomwe ilipo

8.2 Kuwongolera koyenera kwa mainjiniya

Onetsetsani mpweya wokwanira.Gwirani molingana ndi ukhondo wabwino wamafakitale komanso chitetezo.Konzani zotuluka mwadzidzidzi ndi malo ochotsera zoopsa.

8.3 Njira zodzitetezera payekha, monga zida zodzitetezera (PPE)

Chitetezo chamaso / kumaso

Valani chishango chakumaso kapena chitetezo cha maso kuphatikiza zoteteza kupuma.

Chitetezo pakhungu

Magolovesi oteteza.Zovala zoteteza.

Chitetezo cha kupuma

Gwiritsani ntchito mpweya wabwino, utsi wapafupi kapena chitetezo cha kupuma.

Zowopsa za kutentha

palibe deta yomwe ilipo

GAWO 9: Thupi ndi mankhwala katundu ndi chitetezo makhalidwe

GAWO 10: Kukhazikika ndi kuchitapo kanthu

10.1Zochitikanso

Mankhwalawa amapangika pang'onopang'ono mothandizidwa ndi kuwala.Izi zimabweretsa ngozi yamoto kapena kuphulika.Amavunda poyaka ndi kuyatsa.

10.2 Kukhazikika kwamankhwala

Imasanduka mdima ndi kutsitsimuka pa kuyanika kwa nthawi yayitali, imatha kukhazikika ndi madzi 0.1% kapena 1.0% calcium carbonate.

10.3 Kuthekera kwa zochitika zowopsa

Ikhoza kuyaka ikayatsidwa ndi kutentha kapena lawi lamoto, kapena zoziziritsa kukhosi.CHLOROACETONE imasanduka mdima ndi kutsitsimuka ikayatsidwa kwa nthawi yayitali [Merck].Izi zinachitika mu botolo posungira kwa zaka ziwiri pa alumali mu diffused kuwala.Patangopita masiku ochepa botololo litasunthidwa, linaphulika [Ind.Eng.Nkhani 9: 184(1931)].Imakhazikika ndikuwonjezera madzi 0.1% kapena 0.1% CaCO3.

10.4 Zoyenera kupewa

palibe deta yomwe ilipo

10.5Zida zosagwirizana

MBIRI YA MZIMU: Wodzilimbitsa.Chloroacetone idasanduka yakuda pakusungidwa kwa zaka ziwiri payokha pakuwala kosiyana.Patangopita masiku ochepa botolo la chloroacetone litasunthidwa, lidaphulika.Chloroacetone anali atapangidwa polima kukhala chinthu chakuda, Ind. Eng.Nkhani 9: 184(1931).(REACTIVITY, 1999)

10.6 Zinthu zowola zowopsa

Ukatenthedwa kuti uwole umatulutsa utsi wapoizoni kwambiri.

GAWO 11: Zambiri za Toxicological

Pachimake kawopsedwe

• Pakamwa: LD50 Khoswe pakamwa 100 mg/kg
• Kukoka mpweya: LC50 Rat inhalation 262 ppm/1 hr
• Dermal: palibe deta yomwe ilipo

Khungu dzimbiri / kuyabwa

palibe deta yomwe ilipo

Kuwonongeka kwakukulu kwa maso/kupsa mtima

palibe deta yomwe ilipo

Kulimbikitsa kupuma kapena khungu

palibe deta yomwe ilipo

Germ cell mutagenicity

palibe deta yomwe ilipo

Carcinogenicity

palibe deta yomwe ilipo

Ubereki kawopsedwe

palibe deta yomwe ilipo

STOT-kuwonetseredwa kamodzi

Lachrymation.Mankhwalawa amawononga kwambiri maso, khungu ndi kupuma.

STOT-kubwerezabwereza

palibe deta yomwe ilipo

Chiwopsezo cha matenda

Kuyipitsidwa koyipa kwa mpweya kumatha kufikika mwachangu kwambiri pakuwuka kwa chinthu ichi pa 20°C.

GAWO 12: Zambiri zokhudza chilengedwe

12.1 Poizoni

• Kuopsa kwa nsomba: palibe deta yomwe ilipo
• Kuopsa kwa daphnia ndi zamoyo zina zam'madzi zam'madzi: palibe deta yomwe ilipo
• Kuopsa kwa algae: palibe deta yomwe ilipo
• Toxicity to microorganisms: palibe deta yomwe ilipo

12.2 Kulimbikira ndi kunyozeka

palibe deta yomwe ilipo

12.3 Kuthekera kwa Bioaccumulative

Chiwerengero cha BCF cha 3 chinawerengedwa mu nsomba za 1-chloro-2-propanone(SRC), pogwiritsa ntchito chipika cha Kow cha 0.02 (1) ndi equation-derived equation (2).Malinga ndi dongosolo la magulu (3), BCF iyi ikuwonetsa kuthekera kwa bioconcentration mu zamoyo zam'madzi ndi kochepa (SRC).

12.4 Kuyenda m'nthaka

Pogwiritsa ntchito njira yoyerekeza yotengera mamolekyu olumikizana ndi ma cell(1), Koc ya 1-chloro-2-propanone ikhoza kuyerekezedwa kukhala 5(SRC).Malinga ndi dongosolo lamagulu(2), mtengo wa Koc uwu ukuwonetsa kuti 1-chloro-2-propanone ikuyembekezeka kukhala ndikuyenda kwambiri m'nthaka.

12.5 Zotsatira zina zoyipa

palibe deta yomwe ilipo

GAWO 13: Malingaliro otaya

13.1 Njira zochotsera

Zogulitsa

Zinthuzi zitha kutayidwa potengera malo ophatikizirapo mankhwala ovomerezeka kapena powotchera molamulidwa ndi kuchapa gasi.Osawononga madzi, zakudya, chakudya kapena mbewu pozisunga kapena kutaya.Osatayira ku ngalande zotayira.

Zopaka zoipitsidwa

Zotengera zimatha kutsukidwa katatu (kapena zofanana) ndikuperekedwa kuti zibwezeretsedwenso kapena kukonzedwanso.Kapenanso, paketiyo imatha kubowoledwa kuti isagwiritsidwe ntchito pazinthu zina ndiyeno nkutayidwa pamalo aukhondo.Kuwotchera koyendetsedwa ndi kupukuta kwa gasi ndikotheka pazida zoyatsira zoyaka.

GAWO 14: Zambiri zamayendedwe

Nambala ya UN 14.1

14.2UN Dzina Loyenera Kutumiza

14.3 Gulu la zoopsa zapaulendo

14.4 Gulu lonyamula katundu, ngati kuli kotheka

14.5 Zowopsa za chilengedwe

14.6Kusamala kwapadera kwa ogwiritsa ntchito

palibe deta yomwe ilipo

14.7 Kuyenda mochulukira molingana ndi zida za IMO

palibe deta yomwe ilipo

GAWO 15: Zambiri zokhudza malamulo

15.1 Malamulo okhudzana ndi chitetezo, thanzi ndi chilengedwe pazamankhwala omwe akufunsidwa

GAWO 16: Mfundo zina

Zambiri pakukonzanso

Mafupikitsidwe ndi ma acronyms

• CAS: Chemical Abstracts Service
• ADR: Mgwirizano waku Europe wokhudza Kunyamula Katundu Woopsa Panjira Padziko Lonse
• RID: Malamulo okhudza Kunyamula Kwapadziko Lonse kwa Katundu Woopsa ndi Sitima
• IMDG: Katundu Woopsa Panyanja Padziko Lonse
• IATA: International Air Transportation Association
• TWA: Nthawi Yolemera Pakati
• STEL: Malire owonekera kwakanthawi kochepa
• LC50: Lethal Concentration 50%
• LD50: Mlingo wa Lethal 50%
• EC50: Kuyikira Kwambiri 50%
• IPCS - The International Chemical Safety Cards (ICSC), webusayiti: http://www.ilo.org/dyn/icsc/showcard.home
• HSDB – Hazardous Substances Data Bank, webusayiti: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• IARC - International Agency for Research on Cancer, webusaitiyi: http://www.iarc.fr/
• eChemPortal – The Global Portal to Information on Chemical Substances yolembedwa ndi OECD, webusayiti: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
• CAMEO Chemicals, webusayiti: http://cameochemicals.noaa.gov/search/simple
• ChemIDplus, webusayiti: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• ERG – Emergency Response Guidebook lolembedwa ndi US Department of Transportation, webusayiti: http://www.phmsa.dot.gov/hazmat/library/erg
• Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• ECHA - European Chemicals Agency, webusayiti: https://echa.europa.eu/

Maumboni

Zambiri

Pambuyo pokhudzana ndi kupanga matuza amadzimadzi amatha kuchedwa mpaka maola angapo adutsa. Malire ophulika sakudziwika m'mabuku, ngakhale kuti chinthucho chikhoza kuyaka ndipo chimakhala ndi flash point <61 ° C. Mtengo wowonetsera ntchito sayenera kupyola panthawi iliyonse ya Chenjezo la fungo likadutsa malire ake ndilosakwanira.Kuwonjezera kokhazikika kapena choletsa kumatha kukhudza toxicological katundu wa mankhwalawa;funsani katswiri.

Mafunso aliwonse okhudzana ndi SDS iyi, Chonde tumizani kufunsa kwanu kwainfo@mit-ivy.com